I tried talking to her as Roy, but after that she was still an enemy, no one could talk to her, and she ran away without stealing anything. did I screw up or am I missing something? This is my first playthrough and I'm on Chapter 6.
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Chad is definitely the best thief, and Astol can be an excellent backup. Cath's pretty damn bad, regardless of promoting or not. She's far underleveled and can't take hits for ****. If thieves could promote, though, Chad would kick some serious ass.
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cath has better stats, but for this game, thief stats outside of speed and movement don't really matter... Chad is the most balanced of the trio of thieves. So if you need anything stolen, he's your man. However, I still prefer to use Cath alongside him when there's a lot of chests... and even though she's underleveled, thieves don't really have to fight anyways... and her speed's still great (most attacks still miss her, yay)