Completing the Pieces of the Past quest gives you access to four Daedra Hearts with two of them respawning. http://www.uesp.net/wiki/Skyrim:Pieces_of_the_Past Enthir at the College of Winterhold also sells two whenever he restocks. One can be found in Kodlak's room in the Jorrvaskr. This one also respawns.
They can sometimes also appear in Alchemists shops.
"It's you Americans. There's something about nipples you hate. If this were Germany, we'd be romping around naked on the stage here." - Peter Molyneux