Long story short I used my golden key, got booted from live and lost my key and the loot. This all happened within 5 mins of opening the chest. I sent an email to 2K and they said create a SHIFT account through the Extras menu. Apparently Gearbox is able to supply you with more keys through SHIFT. I haven't confirmed this yet but I will try tonight after work.
XBL GT: Mocity Gangsta Currently Playing: Borderlands 2, Dungeon Fighter Live, Marvel Vs Capcom 2- "Rise Above"