Golem: Earthquake Rock Blast / Stone Edge Strength [whatever]
Alakazam: Psychic [any other elemental special attacks]
Arcanine: (don't use the Fire Stone until you've got all the moves you want from Growlithe's natural level-up set!) If you want Flare Blitz you'll have to wait until Level 48 before evolving. I personally don't like recoil moves in-game though. Flamethrower Extremespeed (Arcanine learns at Lv39, can be gotton from move re-learner though after evolving) Crunch [whatever]
Pidgeot: Fly Return / Facade Roost Air Slash (idk, never use Pidgeot)
Ampharos: Discharge Power Gem Signal Beam Thunder Wave
Obviously if you don't mind having Cut, Flash etc on your main team then they can fit in somewhere.
Official Floatzel of the Pokemon XY boards http://i78.photobucket.com/albums/j90/kouta-k6/favouritepokemon_zps877a78e5.png