Round 1 vs. Riku, Nier: Charizard wins easily. Round 2 vs. (probably) Zelda, Lightning: 'Zard might lose to Lightning if she turns out to be awesome, but it's likely pulling through this round as well. Round 3 vs. (probably) Mega Man, Zero/Weighted Companion Cube/? Block: If a block makes it here, 'Zard probably loses to Mega Man, but if Zero is here, chances are he steals votes from Mega Man and Charizard wins the division. Round 4 vs. (probably) Mario, Samus Aran: Mario wins. 'Zard did really well against Mario in 2010 but I don't think it can really win against freaking Mario. Round 5 vs. (probably) Link, Solid Snake/Cloud Strife: Even if Charizard makes it here, Link wins, GG.
Very, very miniscule chance of winning.
Harmony is peace. Peace is unity. Unity is harmony. I tell this to the King Nook. He ask me to leave.