Caitlin. Differently not my favorite Pokegirl, but not too bad either.
As for Smogon, I don't really have a opinion. I have never been into competitive battling, so there has never really been any need for me to go there before. I do plan on battling in gen 6, but even then I'm not going to bother memorizing a bunch of useless rankings. I'll battle with whatever Pokemon I like. OU, UU, whatever else, doesn't matter in the least to me.
I don't hate smogon... The site comes up with some good sets. I do, however, think that adhering to whatever rules and tiers that smogon has in place is ridiculous. Having certain moves and Pokemon banned is stupid.