Nidorino doesn't really learn anything good. Well, you have Horn Attack, which is workable ingame but not at all spectacular, and Horn Drill, which is way too inaccurate and comes way too late (level 53). Oh, and Helping Hand, but I don't think that move sees much use even in competitive 2v2.
The best time to evolve Nidorino is as soon as possible, unless you want to use that Moon Stone on something else.
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