Is there any certain way to get it from him right away? There's nothing I can say to him that gets him to do it. I have the child at heart perk, and all that changed is that he called me his hero once, but that's it. Is there a certain point I have to wait for before I can get it?
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The child at heart perk has nothing to do with the key. It should just be an option that you get when talking to his son after Lucas dies and you dismantled the bomb. Wait - you DID dismantle the bomb right? I mean - that's the point of the mission.
So just ratting Burke out and having Lucas die in vain is pointless / rewardless unless you dismantle the bomb, then talk to his boy.
If you blow up Megaton, Burke hooks you up with a suite in Tenpenny Towers. The suite is nice, the view is nice - the only thing that bothers me is that unlike your house in Megaton where you could Fast Travel to Megaton and walk 10 secs to your house - Tenpenny is more of a pain. You arrive at the gates of the tower, need to get buzzed in, walk inside, take an elevator, go to your room. Urrggh.