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drops are random, even if you kill bosses it will not drop always, for example I killed a random unique boss first time and I only get gray drops, then I re run the place and the same unique boss was there killed him and dropped 3 rares 2 magics and a orb, same with chests and other mobs.
random is random only way to change it is stacking higher quality drops gear and more drops gear too
so what is thebest boss to low level farm? I've not had much time to play so i'm really low.
I farmed Oak in Act 2 quite a few times. Not sure if he's considered a boss or not but a bunch of items drop whenever I kill him. He spawns right next to a waypoint so you can kill him like twice a minute.