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I found one doing Alduins Wall quest. The sword was called Dragon Bane it was with a complete set of blade armor, upgraded both.. Pretty sweet sword, does some major damage! Thats the only one i have found so far, unless i just didnt realize what it was.
There's another unique one called "Bolar's (or Bothars?) Honor Blade" or something close to that in a cave somewhere's. Can't recall where but I've found it with all 3 games I've started. I also used a non-magical one to create my own, but i can't remember if it was the one from the riverwood inn or not.