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S-Tier: -Superman (obviously, being DC's Ryu they designed him to be that way purposely) -Solomon Grundy (the Zangief tier...both can be pretty deadly in the hands of a pro) -Green Arrow (obviously with all those tricks and traps he's going to be pretty high) -Sinestro (I have a feeling they didn't show off EVERYTHING with that video...)
A-Tier: -Lex Luthor (he's going to be an advanced character but really tough) -Catwoman (just look at the combos from her trailer, she's going to be good) -Green Lantern (can also be 'S' tier but haven't seen that potential yet) -Cyborg (spam friendly with that gun and self-healing) -Aquaman (that damned stabby trident, he's going to be a tough one) -Joker (for some reason I think he's going to be a pretty tough character to beat) -Flash (so obvious...most spammed character in MK vs DC will remain in Injustice) -Shazam (reeks of Raiden...pro Raiden players are incredibly hard to beat)
B-Tier: -Batman (just doesn't look as effective as the other characters) -Wonder Woman (same with Batman although played right she can be) -Deathstroke (seems like a spam with those guns but probably looks more badass in the vids than he is in the game)
C-Tier: -Hawkgirl (looks promising but that video underwhelmed her so much) -Nightwing (nothing really stuck out to me with him other than a cool fighting style. Cool doesn't count in tiers though)
D-Tier: -Bane (doesn't look effective, a poor man's Hugo) -Harley Quinn (has been underwhelming since she was announced sadly)
Injustice: Gods Among Us Most Wanted: Black Canary, Steel, Martian Manhunter, Captain Cold, Livewire, Circe, Zatanna, Star Sapphire, Grodd & Poison Ivy