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The pattern I've noticed is that a lot of people tend to play GW after they've given up on other MMO's due to Guild war focusing on other things than the usual grind race. That could partly explain why some find GW players more mature, but if I were to guess I'd say it has more to do with the instances limiting the amount of immature players you'll bump into.
Hyrule geography for beginners: 21% plains, 10% woodland 7% mountains, 5% desert and 57% ancient temples