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You get the highest VATs percentage when aiming at the tail. It is also weaker than most of the other parts.
A tip for fast enemies is to drop a land mine between you and it and back up a bit. The landmine will usually cause a lag crippling injury slowing the enemy down. The dart gun does not cripple a radscorpion as the poison on the dart is radscorpion poison.
Most energy weapons can instant kill with a critical hit.
When also else fails.. NUKE IT!
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